Q1.
Can you now say that elements with different atomic numbers are distinct from each other, and the atomic number uniquely identifies an element?
Answer
Yes. The atomic number Z uniquely identifies an element, and two atoms with different Z are always different elements.
- Z = 1 → hydrogen; Z = 2 → helium; Z = 11 → sodium. There is no second element with Z = 11.
- Nothing else works this way. The mass number does not identify an element — 40Ar, 40K and 40Ca all have A = 40 but are three different elements (isobars).
- The neutron number does not identify it either — 126C, 136C and 146C have 6, 7 and 8 neutrons and are all carbon (isotopes).
Why it happens: in a neutral atom the number of electrons equals the number of protons, so Z fixes the electron count. The electron count fixes the electronic configuration, which fixes the number of valence electrons — and valence electrons decide chemistry. Change Z and you change the chemistry; change only the neutrons and the chemistry stays the same.