Q1.
In NH₃ (ammonia) and MgCl₂ (magnesium chloride), what will be the combining capacities of nitrogen and magnesium respectively?
Answer
Nitrogen: 3. Magnesium: 2.
Rule: the combining capacity of an element is the number of hydrogen or chlorine atoms that combine with one of its atoms — because hydrogen and chlorine each have a combining capacity of one.
In NH3: one N atom combines with 3 H atoms
⇒ combining capacity of nitrogen = 3
In MgCl2: one Mg atom combines with 2 Cl atoms
⇒ combining capacity of magnesium = 2
⇒ combining capacity of nitrogen = 3
In MgCl2: one Mg atom combines with 2 Cl atoms
⇒ combining capacity of magnesium = 2
Cross-check with the electronic configurations — the two methods must agree:
| Element | Configuration | Valence electrons | To complete the octet | Valency |
|---|---|---|---|---|
| Nitrogen (Z = 7) | 2, 5 | 5 | needs 3 more | 3 ✓ |
| Magnesium (Z = 12) | 2, 8, 2 | 2 | loses its 2 outer electrons | 2 ✓ |
Why it happens: the formula of a compound is not arbitrary — it is fixed by how many electrons each atom must gain, lose or share to reach a stable octet. Nitrogen is 3 electrons short of 8, so it shares with three hydrogens. Magnesium has 2 electrons more than a stable shell, so it hands one each to two chlorine atoms, each of which was 1 electron short.