Q17.
Two different atoms have 11 protons each, but one has 12 neutrons, and the other has 13 neutrons. How do their atomic numbers and mass numbers compare? Are they the same element or different elements?
Answer
Same atomic number, different mass numbers — they are the same element (sodium), and they are isotopes of each other.
Atomic number Z = number of protons
First atom: Z = 11 Second atom: Z = 11 → equal
Mass number A = p+ + n0
First atom: A = 11 + 12 = 23 → 2311Na
Second atom: A = 11 + 13 = 24 → 2411Na
→ different, by 1
First atom: Z = 11 Second atom: Z = 11 → equal
Mass number A = p+ + n0
First atom: A = 11 + 12 = 23 → 2311Na
Second atom: A = 11 + 13 = 24 → 2411Na
→ different, by 1
Z = 11 in both cases, and Z is what fixes the identity of an element, so both are sodium. Same Z, different A is the definition of isotopes.
Why it happens: both atoms are neutral, so both have 11 electrons, arranged 2, 8, 1. Identical valence shell ⇒ identical chemistry. Both are soft metals that react vigorously with water. The extra neutron only makes the second atom about 4% heavier, which shows up in physical properties, not chemical ones.
Check it yourself: would the answer change if one atom had 11 protons and the other 12? Yes, completely — 11 protons is sodium and 12 is magnesium. Different elements, and they would not be isotopes at all.