Aim: to show that water from different sources always splits into hydrogen and oxygen in the same fixed ratio — a direct test of the Law of Constant Proportions.
Principle. Passing a direct current through water decomposes it. Hydrogen collects at the cathode (negative electrode) and oxygen at the anode. If water is always H₂O, the volume ratio must always be 2 : 1, whatever the source.
Apparatus: a Hofmann voltameter (or a plastic tub with two inverted graduated test tubes over two carbon electrodes), a 9 V battery, dilute sulfuric acid, and water samples from four sources — tap, rain, borewell and river.
Method
- Filter and then distil each sample. This is the step that decides the experiment — the dissolved salts must go, or you will be electrolysing a solution, not water.
- Fill the apparatus with the first distilled sample. Add 3–4 drops of dilute sulfuric acid to make it conduct. Add exactly the same amount to every sample.
- Fill both graduated tubes completely, invert them over the electrodes, and connect the 9 V battery.
- Run for a fixed time — say 10 minutes — and read the volume of gas collected in each tube.
- Test the gases: the larger volume gives a squeaky pop with a lighted splint (hydrogen); the smaller one relights a glowing splint (oxygen).
- Repeat, washing the apparatus thoroughly, for each of the four sources.
Sample observations
| Source of water | Volume of H₂ | Volume of O₂ | Ratio H₂ : O₂ |
|---|---|---|---|
| Tap water | 20.0 mL | 10.0 mL | 2 : 1 |
| Rain water | 18.2 mL | 9.1 mL | 2 : 1 |
| Borewell water | 21.4 mL | 10.6 mL | 2 : 1 |
| River water | 19.6 mL | 9.9 mL | 2 : 1 |
Conclusion. The total volume varies from run to run — that only reflects small differences in current and time — but the ratio is 2 : 1 every single time. Water from every source has the same composition.
→ 2 molecules of H₂ : 1 molecule of O₂ → 4 H atoms : 2 O atoms → H₂O
By mass: (4 × 1 u) : (2 × 16 u) = 4 : 32 = 1 : 8 ✓
Controls to keep the test honest: the same volume of acid in every run, the same electrodes, the same current and the same time; and read the volumes only after the tubes have cooled and the bubbles have cleared.