Because they contain no charged particles that are free to move — neither ions nor free electrons.
A current is nothing but charge in motion. For a substance to conduct, it must supply mobile charge carriers. Camphor and naphthalene supply none:
- They are made of electrically neutral molecules. Every electron in them is either locked in a shared pair inside a covalent bond or sitting as a lone pair on an atom — none of them can wander off through the solid.
- They are insoluble in water, so they never get the chance to release ions into solution the way sodium chloride does.
- Even when melted, they stay as molecules. Melting camphor loosens the molecules from one another, but it does not break the covalent bonds inside them, so still no ions appear.